Enhancement of magnetization and optical properties of CuFe2O4/ZnFe2O4 core/shell nanostructure | Scientific Reports

Oct 21, 2024

Scientific Reports volume 14, Article number: 6935 (2024) Cite this article

1211 Accesses

3 Citations

Metrics details

In this work, core/shell of CuFe2O4/ZnFe2O4 nanostructure composite was prepared by hydrothermal method. X-ray diffraction (XRD) analysis, transmission electron microscope imaging, energy dispersive X-ray (EDX), and Fourier transform infrared techniques were used to prove the phase formation, morphology, elemental analysis, and cation distribution of core/shell structure, respectively. Furthermore, measurement of the optical properties proved the decrease of photoluminescence (PL) efficiency. The magnetic measurements showed an enhancement of the magnetization by about 63% relative to pure Cu ferrite, and the magnetization curve exhibited superparamagnetic behavior. These results were explained in terms of the depression of the magnetic dead layer thickness in the core/shell structure. The results unleash the promising applications of the prepared samples as transformer cores in the high frequency range and as a photocatalytic agent for water purification and hydrogen production.

Nano ferrites (NFs) have been regarded as crucial materials for modern technologies in the last 20 years. The study of the chemical and physical properties of nano-ferrite (NF) materials is intricate because of the impact of miniaturizing the structure on the magnetic, electric, and optical features that these materials possess1,2. In addition, the dopant ions, chemical composition, synthesis procedures, thermal treatments, and shape play a crucial role in determining their characteristics. Applications of NFs include medical, telecommunications, wave absorbers, data recording, chemical sensors, microwave devices, sustainable sources, giant magnetoresistive devices (GMR), magnetic resonance imaging (MRI) technology, drug delivery systems, etc2,3,4,5,6,7.

Intense research is currently in progress on the synthesis and application of magnetic nanoparticles core/shell composites. These important materials have been synthesized and investigated by several research groups during the last few years. There are many reviews in the literature about core/shell ferrite nanoparticles, discussing their different synthesis conditions and techniques8,9,10,11 and the obtained properties including magnetic12, magneto-electric13 and optical properties13. Their applications in drug delivery13, water remediation, and catalysis14,15 are also subject to intense research. Zinc ferrite (ZnFe2O4) is used as semiconductor photo-catalyst for various processes, due to its ability to absorb visible light and its high efficiency, which shows potentially wide applications in photoinduced transformer, photoelectrochemical cells and photochemical hydrogen production16,17,18,19,20. Moreover, ZnFe2O4 as a core and ZnO as a shell were investigated by Rong Shao et al. for photocatalysis and was prepared via solvothermal method21. The photocatalytic activity of the novel ZnFe2O4/ZnO sample was higher than that of pure ZnO and the highest photocatalytic activity was observed in samples prepared with a 1:10 molar ratio of ZnFe2O4 to ZnO. ZnFe2O4/SiO2/TiO2 nanoparticles as magnetic photocatalysts for etodolac degradation was studied by Eryka Mrotek et al.14. The coupling between Zn ferrite and oxide materials significantly enhanced etodolac breakdown and mineralization as evaluated by TOC removal. As an alternative to more often utilized metal oxides, spinel copper ferrite (CuFe2O4) has recently been used for very wide range of applications as a photoanode for water oxidation, photocathodes for hydrogen evolution, photocatalyst and sensor due to its narrow band gap (1.54–1.9 eV)22,23. Thu Uyen Tran Thi et al.24 synthesized CuFe2O4/Fe2O3 core/shell to study the effective photo-Fenton-like catalysts for the methylene blue degradation process using oxalic acid as a radical generator. It was noticed that catalytic performance was two times greater than that of the CuFe2O4 sample in a 1:2 CuFe2O4/Fe2O3, with a rate constant of 2.103 h−1 when exposed to UVA light and 0.542 h−1 when exposed to visible light. Using laser Raman spectroscopy, Balaji et al.25 examined the formation of CuFe2O4-polyaniline core/shell nanocomposites prepared by in situ polymerization method. Shuo-Hsiu Kuo et al.26 fabricated Cu ferrite-polymer as core/shell nanoparticles to study cervical cancer cell photodynamic ablation. It was found that the superparamagnetic characteristics of Cu ferrite-polymer are promising MRI contrast agents and may be utilized as a Fenton catalyst to transform H2O2 into ROS.

Thus, based on the above survey, there are very few reports on the properties of CuFe2O4/ZnFe2O4 core/shell. Herein, hydrothermal technique was used to prepare bare ZnFe2O4 and CuFe2O4 nanoparticles, as well as CuFe2O4/ZnFe2O4 core/shell nanoparticles for studying the structural, optical, and magnetic properties of these three samples.

The iron (III) nitrate nonahydrate (Fe(NO3)3.9H2O) (99.99%, Alfa Aesar), copper (II) nitrate hexahydrate (Cu(NO3)2.6H2O) (99.5% LOBA Chemie), zinc (II) nitrate hexahydrate (Zn(NO3)2.6H2O) (98% LOBA Chemie), and sodium hydroxide (NaOH) purchased from Sigma Aldrich utilized in the preparation of the pure and core/shell nano-ferrites were all of analytical grade, and deionized water was used as the solvent.

Copper ferrite nanoparticles were synthesized through the dissolution of (Cu(NO3)2 · 6H2O), and (Fe(NO3)3 · 9H2O) by molar ratio 1:2 in deionized water. The pH of the precursor solution was adjusted to a value of 10 by drop-wise addition of a sodium hydroxide (NaOH) solution while vigorously stirring. After being stirred continuously for one hour, the solution was transferred into a 100 mL Teflon-lined stainless-steel autoclave. The autoclave was subjected to a thermal treatment at a temperature of 180 °C for 18 h. Following the completion of the hydrothermal reaction, the autoclave was subsequently removed from the reaction environment and allowed to cool to ambient temperature. The same process was employed for the preparation of zinc ferrite nanoparticles. The resulting product of both CuFe2O4 and ZnFe2O4 was subjected to filtration and subsequent washing with water, repeated multiple times until the pH reached a value of 7.0. After drying at 95 °C for 3 h, the CuFe2O4 powder was divided into two portions. The first portion was used as bare CuFe2O4, and the other portion served as the core for the core/shell composite sample. The chemical reaction for the preparation of both copper ferrite (CoFe2O4) and zinc ferrite (ZnFe2O4) nanoparticles is as follows:

To coat the surface of the prepared CuFe2O4 (core) with ZnFe2O4 (as shell), 1 gm of CuFe2O4 nanoparticles was transferred to the autoclave along with the precursors for the synthesis of ZnFe2O4. The mass ratio between ZnFe2O4 to CuFe2O4 is 2:1. Here, CuFe2O4 nanoparticles serve as seeds for the crystal growth of ZnFe2O4 because of the good lattice matching between the core and the shell. The resulting product was subjected to filtration and subsequently washed multiple times with water until the pH of the solution reached 7.0. Finally, the core/shell sample was dried at 95 °C for 3 h. Figure 1 illustrates a schematic diagram for the synthesis of the core/shell composite samples by hydrothermal method.

Schematic diagram for the synthesis of the core/shell composite samples by hydrothermal method.

X-ray diffraction (XRD; BrukerAXSD8Advance, Bruker, Germany) was used to characterize the samples. For studying the microstructure and estimating the particle size, a transmission electron microscope (henceforth, TEM) (Jeol–Jem 1230 electron microscope) was used. Energy Dispersive X-ray (EDX) measurements were carried out using a TESCAN VEGA COMPACT SEM with Tungsten filament as an electron source and an attached EDX detector (Czech Republic). Fourier transform infrared spectroscopy (FTIR) was performed at room temperature in transmission mode (Spectrometer JASCO, 6300, Japan)) in the range of 400–4000 cm−1. Room temperature photoluminescence (PL) spectra with an excitation wavelength of 325 nm were obtained using a (FLUOROMAX-2 spectrofluorometer, JOBIN YVON—SPEX, New Jersey; USA). A room-temperature vibrating sample magnetometer (VSM) (model Lake Shore no. 7410 US) was used to measure the magnetic properties in a field up to 20 kG. Finally, the assessment of the AC loss of the samples when exposed to an AC magnetic field with a frequency of 66.5 kHz and a magnetic field strength of 1.45 kAm-1; was conducted by measuring the increase in temperature over time.

Figure 2 shows the X-ray diffraction patterns of Cu ferrite (CuFe2O4), Zn ferrite (ZnFe2O4), and CuFe2O4/ZnFe2O4 core/shell samples. All of the reflection peaks match well with the typical JCPDS cards No. 34-042527 and 22-101228 of pure CuFe2O4 and ZnFe2O4 phases, respectively, with no external peaks indicating that all the produced samples crystallized as a single-phase cubic structure with Fd-3m space group29. On the other hand, a small phase percentage of the hematite (α-Fe2O3) in the core/shell sample was obtained5,30. Furthermore, all samples were subjected to Rietveld analysis using the MAUD software programme31 in order to accurately characterize the crystal structure and determine the lattice constant (\(a\)fit.) and crystallite size (\(L_{fit. }\)). Figure 3 illustrates the outcomes of the fitted profile. The process of refinement was carried out iteratively until reaching convergence with a goodness factor approaching one, approximately2,29. Table 1 includes both the (\(a\)fit.) and (\(L_{fit. }\)) values with the corresponding refinement standard deviation parameter for the investigated samples. It was found from refinement fitting that the phase percentages of ZnFe2O4, CuFe2O4, and hematite (α-Fe2O3) are (82.25%), (2.33%) and (15.42%), respectively. Such a result confirms that the CuFe2O4 was covered by ZnFe2O4. The calculated lattice constant (\(a\)cal.) for the three samples was computed using the following relation:

where dhkl denotes the inter-planar spacing in the XRD pattern and (hkl) are the Miller indices of the main peaks. In addition, the Williamson-Hall (W–H) Eq.32 is used to obtain the calculated average crystallite size (\(L_{cal. }\)) as well as the micro strain (ε) for the three samples. The calculated values of (\(a\)cal.) and (\(L_{cal. }\)) are also given in Table 1. One can see that, the lattice parameter values for CuFe2O4 and ZnFe2O4 are consistent with those reported in18,20,27. In addition to this, the lattice parameter of CuFe2O4/ZnFe2O4 core/shell is quite similar to that of pure ZnFe2O4.The lattice matching between ZnFe2O4 and CuFe2O4 causes ZnFe2O4 crystals to grow as a shell on CuFe2O4 as a seed33.

XRD patterns of CuFe2O4, ZnFe2O4 and CuFe2O4/ZnFe2O4 core/shell samples.

Rietveld refinement profile for (a) ZnFe2O4, (b) CuFe2O4, and (c) CuFe2O4/ZnFe2O4 core/shell nanoparticles using MAUD program.

In addition, when considering the crystallite size of CuFe2O4/ZnFe2O4 in comparison to both bare ferrites; it becomes evident that the crystallite size of the core/shell sample is greater than that of bare ZnFe2O4 and CuFe2O4 by approximately 9 nm. This observation provides evidence for the formation of core/shell nanoparticles. Furthermore, it can be observed that the lattice strain—Table 1—in the CuFe2O4/ZnFe2O4 core/shell is higher compared to that of the pure CuFe2O4. This increase in lattice strain can be attributed to the minimal difference in lattice parameters between ZnFe2O4 and CuFe2O4, providing further evidence for the presence of ZnFe2O4 as a shell surrounding CuFe2O433.

Figure 4 presents transmission electron microscopy (TEM) images depicting the CuFe2O4, ZnFe2O4 nanoparticles, and CuFe2O4/ZnFe2O4 core/shell. One can see that the shape and particle size distribution of the ferrite particles are uniform. As shown in Fig. 4, the histogram for bare ferrites and core/shell nanoparticles was used to determine the particle size distribution. The particle size was found to be approximately 9, 12 and 25 nm, with an error margin of 2 nm for CuFe2O4, ZnFe2O4, and CuFe2O4/ZnFe2O4, respectively. These values align well with the measurements obtained from X-ray diffraction (XRD). The uniform shell thickness is around 7 nm thick, while the core size is about 18 nm. However, particle agglomeration occurs as a result of magnetostatic interactions between particles or because nanoparticles experience a permanent magnetic moment proportionate to their volume.

TEM images of (a) CuFe2O4, (b) ZnFe2O4 nanoparticles, and (c) CuFe2O4/ZnFe2O4 core/shell.

Furthermore, Fig. 5 illustrates the quantitative EDX analysis conducted at different points and extensive regions to ascertain the elemental composition of the three samples. The results obtained after applying ZAF correction indicated that the atomic weight of the synthesized materials is consistent with the expected stoichiometric ratios. The presence of some Ca peaks in the EDX spectra of both bare ferrites may indicate the presence of small amounts (less than 2.4% by weight) of chemical impurities coming from the precursor materials. Therefore, the samples can be regarded as pure and in strong accordance with the XRD results. From Fig. 6, one can see that at the same point, the Cu and Zn elements, in core/shell sample, have weight percentages of 8.93, and 19.52, respectively, which were confirmed by the XRD refinement analysis. Such a result gives confidence to the formation of core/shell nanoparticles.

EDX spectra and Mapping of (a) CuFe2O4/ZnFe2O4 core/shell, (b) ZnFe2O4, and (c) CuFe2O4 nanoparticles.

Mapping images of CuFe2O4/ZnFe2O4 core/shell nanoparticles.

Figure 7 displays the Fourier transform infrared (FTIR) spectrum of the investigated samples to confirm the spinel ferrite phase formation and to ensure that there are no chemical residues inside the prepared nanoparticles. The spectrum is presented within the wave-number range of 400–4000 cm−1.The infrared spectra of the compound exhibit two prominent absorption bands, namely υt which are observed at wavenumbers (≈ 560 to 565 cm−1) assigned to the tetrahedral complexes and υo at wavenumbers (≈ 400 to 450 cm−1) which associated with the vibrations of high valence cation(s) (such as Fe3+–O2−) that occupy the octahedral site34. The two vibration bands observed in this study are associated with the intrinsic vibrations occurring at the octahedral and tetrahedral sites within the spinel structure, respectively34. Both the strong wide band at 3420 cm−1 and the weaker band at 1642 cm−1 result from the interaction of O–H stretching vibrations with H bonds35. Furthermore, the peaks observed at wavenumbers 3427 cm−1 and 1632 cm−1 are attributed to bending and stretching vibrations of H–O–H which confirms the existence of absorbed water2,17,19.

FTIR spectra of CuFe2O4, ZnFe2O4 and CuFe2O4/ZnFe2O4 core/shell nanoparticles.

Photoluminescence (PL) is used to study the electronic interaction at the surface between the core and shell structure. Figure 8 shows the PL emission spectra carried out at the excitation wavelength of 325 nm (Eexc. = 3.8eV), which is greater than the energy gaps of Zn ferrite (2.1 eV)28 and Cu ferrite (1.9 eV)22,23. One can see that the PL signal is very strong for Cu ferrite while it is very weak for Zn ferrite. This means that the recombination rate between electron–hole pairs is much faster for Cu ferrite than in Zn ferrite. On the other side, the PL signal for core/shell structure is slightly decreased; because of a generation of trapping states at the interface between the core and shell ferrites, as well as it was observed to exhibit a slight redshift, indicating a decrease in wavelength. This could be attributed to the quantum confinement effect18,28.The proposed electronic structure is shown in Fig. 9. The modification of PL signal for the core/shell structure could be useful for hydrogen production as well as for water purification as photocatalysis.

PL spectra for CuFe2O4, ZnFe2O4 and CuFe2O4/ZnFe2O4 core/shell nanoparticles.

Schematic represents the band diagrams of both ferrites (left) and the trapping state occurs due to the interface between the core and shell (right).

Figure 10 shows the hysteresis loop for the investigated samples. One can see that, the Cu ferrite (CuFe2O4) sample has identical ferromagnetic behavior with fast saturation at magnetic field intensity \({ } \ge 5000 G\).

Magnetic hysteresis loop of CuFe2O4, ZnFe2O4 and CuFe2O4/ZnFe2O4 core/shell nanoparticles.

Additionally, the magnetization data extracted from hysteresis loop were fitted employing the Law of approach to saturation (LAS) using the least squares approach, which is demonstrated by the following equation2,29.

The parameter (B) is induced by crystal anisotropy, which is related to the cubic anisotropy constant. The above equation describes the relation between the field (H) and (M) in the high field region as illustrated in Fig. 11a. The fitting curves (M vs. 1/H2 data) for CuFe2O4, ZnFe2O4 and CuFe2O4/ZnFe2O4 core/shell nanoparticles are shown in Fig. 11b. The value of the obtained saturated magnetization (Ms) is about 7.6 emu/g (Table 1), which is lower than the Ms value of bulk Cu ferrite (≈ 60 emu/g)36,37,38. This reduction could be explained by the presence of a magnetic dead layer as a result of a high surface-to-volume ratio due to the discontinuity of the magnetic moments at the surface of the nanoparticles and the presence of random canting of particle surface spins at the surface 39,40,41. However, by comparing both values of saturated magnetization, the thickness of the dead layer (δ) could be calculated according to the following relations:

(a) ‘Law of approach’ fit to M versus H, and (b) linear fit of M versus 1/H2 for CuFe2O4, ZnFe2O4 and CuFe2O4/ZnFe2O4 core/shell nanoparticles.

The Zn ferrites sample exhibits superparamagnetic behavior, and by Langevin function fitting42,43, Ms was found to be around 10 emu/g which is in agreement with the bulk saturated magnetization value44,45, which means there is no magnetic dead layer due to the antiferromagnetic behavior of Zn ferrite. On the other hand, for the CuFe2O4/ZnFe2O4 core/shell nanostructure, the saturated magnetization Ms increased dramatically up to 12.4 emu/g, which is an interesting behavior. This increasing behavior is not simply a linear combination of the magnetization values of both Cu ferrite and Zn ferrite. Alternately, it can be represented as follows:

The last term in the above equation is the increase in magnetization due to the interfacial effects between the core and shell. Substituting the experimental values of Ms in the above equation, we get:

Then, the value of Ms(Cu/Zn) = 4.01 emu/g. The enhancement of the magnetization could be explained in terms of the decrease in thickness of the magnetic dead layer due to the continuity of the interaction at the surface of core Cu ferrite and Zn ferrite as a shell. Furthermore, in deep sight, the hysteresis loop of the core/shell sample displays the failure to reach magnetic saturation. This behavior could be explained in terms of the presence of Fe2O3 as a weakly ferromagnetic or antiferromagnetic phase that initiates the superparamagnetic tendency, i.e., it resists the magnetic moment rotation due to the limited response of the antiferromagnetic moments to the applied field46, as well as, it suggests some degree of non-collinear spin structure, which is normally described by a core/shell particle model47. It’s valuable to note that the core/shell sample also has superparamagnetic behavior (i.e., Hc = 0).

One of the most important studies is the magnetic losses of the material at high frequency. The magnetic loss or heating ability is determined by measuring the increase in temperature over time for the three samples. The design and operation of the used induction heating circuit are described in detail elsewhere48,49. Figure 12 depicts the rise in temperature of the investigated samples with time within for an exposure duration of 10 min. It is evident that the Cu ferrite sample has the maximum magnetic loss (the slope of T vs. time) while the Zn ferrite, as expected because of its antiferromagnetic behavior, has the least loss. Typically, hysteresis loss, eddy loss, Néel relaxation, and the Brownian rotation all contribute to the magnetic loss in samples of multi-domain magnetic NPs29,50. The generation of hysteresis loss can be attributed to the movements and rotations of magnetic domain walls51. When a material undergoes sinusoidal magnetization, the voltage induced within the material exhibits an opposite polarity compared to the voltages responsible for generating the magnetizing current and the alternating magnetic field. Consequently, circular currents are induced, which give rise to magnetic fields that are oriented in the opposite direction to that of the initial current. The eddy current exhibits its maximum strength at the core of the magnetic material particle. Moreover, it is worth noting that hysteresis loss is primarily observed in particles with large crystallites and multiple domains, whereas relaxation loss is observed in particles with a single domain52. However, it has been established that the hysteresis and eddy current heating effects can be ignored when dealing with particles with sizes smaller than 20 nm29. On the other hand, Néel and Brownian relaxations cause magnetic loss in superparamagnetic materials (i.e., Hc = 0). As the sample is in powder form, Brownian relaxation is ruled out because it occurs by particle rotation in the carrier liquid. Hence, for the Cu ferrite sample, we suggested that the primary mechanism responsible magnetic loss is the Néel relaxation53,54.

Temperature rise with time for CuFe2O4, ZnFe2O4 and CuFe2O4/ZnFe2O4 core/shell nanoparticles.

The temperature of the powder samples (CuFe2O4 and core/shell) increased initially and ultimately reached a state of saturation. The measurement of the heat ability of the samples (ΔT/Δt) is obtained by calculating the slope from the linear segment as shown in Fig. 12. It is valuable to notice that the magnetic loss of core/shell structure decreased in comparison to the bare CuFe2O4 although its magnetization increased. This property renders the core/shell structure very useful in high frequencies applications. The high magnetization value of the core/shell sample is not reflected on its heating ability. The presence of the Fe2O3 phase, as previously mentioned in relation to hysteresis measurements, reduces the magnetic loss (the samples' heating ability) by obstructing the rotation of magnetic moments in response to an external magnetic field55. This, in turn, reduces the Néel rotation in response to a high-frequency field.

Core/shell magnetic nanoparticles were synthesized using hydrothermal technique. The mechanism of core/shell formation is determined by the lattice matching between both CuFe2O4 and ZnFe2O4 nanoparticles. Moreover, the PL signal of core/shell nanoparticles was found to be between bare ferrites; CuFe2O4 and ZnFe2O4. Like change of the PL signal for the core/shell structure compared to both pure ferrite nanoparticles could be advantageous for the creation of hydrogen as well as for the photocatalytic purification of water. The Law of approach to saturation (LAS) was used to deduce the accurate magnetization values for the investigated samples. The magnetization of the core/shell nanocomposite was found to be approximately 63% higher than that of pure Cu ferrite, while the magnetic loss decreased. It is important to acknowledge that the core/shell sample exhibits superparamagnetic behavior. This property holds great promise for various applications.

The data that support the findings of this study are available from the corresponding author upon request.

Baykal, A. et al. Magnetic properties and hyperfine interactions of Co1-2xNixMnxFe2O4 nanoparticles. Ceram. Int. 43, 4746–4752 (2017).

Article CAS Google Scholar

Faramawy, A. M., Elsayed, H. & Agami, W. R. Correlation between structure, cation distribution, elastic, and magnetic properties for Bi3+ substituted Mn–Zn ferrite nanoparticles. Mater. Chem. Phys. 314, 128939 (2024).

Article CAS Google Scholar

Amir, M., Baykal, A., Güner, S., Güngüneş, H. & Sözeri, H. Magneto-optical investigation and hyperfine interactions of copper substituted Fe3O4 nanoparticles. Ceram. Int. 42, 5650–5658 (2016).

Article CAS Google Scholar

Güner, S. et al. Synthesis and characterization of oleylamine capped MnxFe1-xFe2O4nanocomposite: Magneto-optical properties, cation distribution and hyperfine interactions. J. Alloys Compd. 688, 675–686 (2016).

Article Google Scholar

Kahil, H., Faramawy, A., El-Sayed, H. & Abdel-Sattar, A. Magnetic properties and sar for gadolinium-doped iron oxide nanoparticles prepared by hydrothermal method. Crystals 11, 1153 (2021).

Article CAS Google Scholar

Faramawy, A. M. et al. Unveiling the effect of Gd3+ doping on enriching the structural, magnetic, optical, and dielectric properties of biocompatible hematite nanoparticles. J. Alloys Compd. 974, 172845 (2024).

Article CAS Google Scholar

Xiao, N. et al. T1–T2 dual-modal MRI of brain gliomas using PEGylated Gd-doped iron oxide nanoparticles. J. Colloid Interface Sci. 417, 159–165 (2014).

Article ADS CAS PubMed Google Scholar

Gavrilov-Isaac, V. et al. Synthesis of trimagnetic multishell MnFe2O4@CoFe2O4@NiFe2O4 nanoparticles. Small 11, 2614–2618 (2015).

Article CAS PubMed Google Scholar

Wei, S. et al. Multifunctional composite core–shell nanoparticles. Nanoscale 3, 4474 (2011).

Article ADS CAS PubMed Google Scholar

Sanna Angotzi, M. et al. Spinel ferrite core-shell nanostructures by a versatile solvothermal seed-mediated growth approach and study of their nanointerfaces. ACS Nano 11, 7889–7900 (2017).

Article CAS PubMed Google Scholar

Morrison, S. A., Cahill, C. L., Carpenter, E. E., Calvin, S. & Harris, V. G. Atomic engineering of mixed ferrite and core-shell nanoparticles. J. Nanosci. Nanotechnol. 5, 1323–1344 (2005).

Article CAS PubMed Google Scholar

Gabal, M. A., Al-Juaid, A. A., El-Rashed, S., Hussein, M. A. & Al-Angari, Y. M. Polyaniline/Co0.6Zn0.4Fe2O4 core-shell nano-composites: Synthesis, characterization and properties. J. Alloys Compd. 747, 83–90 (2018).

Article CAS Google Scholar

Record, P. et al. Direct and converse magnetoelectic effect in laminate bonded Terfenol-D-PZT composites. Sens. Actuat. B Chem. 126, 344–349 (2007).

Article ADS CAS Google Scholar

Mrotek, E. et al. Improved degradation of etodolac in the presence of core-shell ZnFe2O4/SiO2/TiO2 magnetic photocatalyst. Sci. Total Environ. 724, 138167 (2020).

Article CAS PubMed Google Scholar

Shao, R., Sun, L., Tang, L. & Zhidong, C. Preparation and characterization of magnetic core–shell ZnFe2O4@ZnO nanoparticles and their application for the photodegradation of methylene blue. Chem. Eng. J. 217, 185–191 (2013).

Article CAS Google Scholar

Tatarchuk, T. et al. Structural, Optical, and Magnetic Properties of Zn-Doped CoFe2O4 Nanoparticles. Nanoscale Res. Lett. 12, (2017).

Taneja, S., Thakur, P., Ravelo, B. & Thakur, A. Nanocrystalline samarium doped nickel-zinc-bismuth ferrites: Investigation of structural, electrical and dielectric properties. Mater. Res. Bull. 154, 111937 (2022).

Article CAS Google Scholar

Tatarchuk, T. R. et al. Effect of cobalt substitution on structural, elastic, magnetic and optical properties of zinc ferrite nanoparticles. J. Alloys Compd. 731, 1256–1266 (2018).

Article CAS Google Scholar

Sundararajan, M., John-Kennedy, L. & Judith-Vijaya, J. Synthesis and characterization of cobalt substituted zinc ferrite nanoparticles by microwave combustion method. J. Nanosci. Nanotechnol. 15, 6719–6728 (2015).

Article CAS PubMed Google Scholar

Chung, P. H. et al. A sensitive visible light photodetector using cobalt-doped zinc ferrite oxide thin films. ACS Appl. Mater. Interfaces 13, 6411–6420 (2021).

Article CAS PubMed Google Scholar

Shao, R., Sun, L., Tang, L. & Zhidong, C. Preparation and characterization of magnetic core-shell ZnFe2O4@ZnO nanoparticles and their application for the photodegradation of methylene blue. Chem. Eng. J. 217, 185–191 (2013).

Article CAS Google Scholar

Park, S. et al. Rapid flame-annealed CuFe2O4 as efficient photocathode for photoelectrochemical hydrogen production. ACS Sustain. Chem. Eng. 7, 5867–5874 (2019).

Article CAS Google Scholar

Liu, Y. et al. Insights into the interfacial carrier behaviour of copper ferrite (CuFe2O4) photoanodes for solar water oxidation. J. Mater. Chem. A 7, 1669–1677 (2019).

Article ADS CAS Google Scholar

Tran Thi, T. U. et al. Synthesis of magnetic CuFe2O4/Fe2O3 core-shell materials and their application in photo-Fenton-like process with oxalic acid as a radical-producing source. J. Asian Ceram. Soc. 9, 1091–1102 (2021).

Article Google Scholar

Balaji, M., Chithra Lekha, P. & Pathinettam Padiyan, D. Core-shell structure in copper ferrite-polyaniline nanocomposite: Confirmation by laser Raman spectra. Vib. Spectrosc. 62, 92–97 (2012).

Article CAS Google Scholar

Kuo, S. H. et al. Fabrication of anisotropic Cu ferrite-polymer coreshell nanoparticles for photodynamic ablation of cervical cancer cells. Nanomaterials 10, 1–19 (2020).

Article ADS Google Scholar

Mulud, F. H., Dahham, N. A. & Waheed, I. F. Synthesis and characterization of copper ferrite nanoparticles. IOP Conf. Ser. Mater. Sci. Eng. 928, 072125 (2020).

Article CAS Google Scholar

Manikandan, A., Kennedy, L. J., Bououdina, M. & Vijaya, J. J. Synthesis, optical and magnetic properties of pure and Co-doped ZnFe2O4 nanoparticles by microwave combustion method. J. Magn. Magn. Mater. 349, 249–258 (2014).

Article ADS CAS Google Scholar

Faramawy, A. M., Mattei, G., Scian, C., Elsayed, H. & Ismail, M. I. M. Cr3+ substituted aluminum cobalt ferrite nanoparticles: Influence of cation distribution on structural and magnetic properties. Phys. Scr. 96, 125849 (2021).

Article ADS Google Scholar

Kant, R., Kumar, D. & Dutta, V. High coercivity α-Fe2O3 nanoparticles prepared by continuous spray pyrolysis. RSC Adv. 5, 52945–52951 (2015).

Article ADS CAS Google Scholar

Lutterotti, L., Gualtieri, A. & Aldrighetti, S. Rietveld refinement using Debye-Scherrer film techniques. Mater. Sci. Forum 228–231, 29–34 (1996).

Article Google Scholar

Williamson, G. K. & Hall, W. H. X-ray line broadening from filed aluminium and wolfram. Acta Metall. 1, 22–31 (1953).

Article CAS Google Scholar

Sattar, A. A., El-Sayed, H. M. & Alsuqia, I. Structural and magnetic properties of CoFe2O4/NiFe2O4 core/shell nanocomposite prepared by the hydrothermal method. J. Magn. Magn. Mater. 395, 89–96 (2015).

Article ADS CAS Google Scholar

Agami, W. R. Composition and temperature dependence of the dielectric properties of (Silicone Rubber/CoZn nanoferrite) composites. Appl. Phys. A Mater. Sci. Process. 127, 1–11 (2021).

ADS Google Scholar

Sathishkumar, G., Venkataraju, C., Murugaraj, R. & Sivakumar, K. Bismuth effect in the structural, magnetic and dielectric properties of CoZn ferrite. J. Mater. Sci. Mater. Electron. 23, 243–250 (2012).

Article CAS Google Scholar

Rashad, M. M., Mohamed, R. M., Ibrahim, M. A., Ismail, L. F. M. & Abdel-Aal, E. A. Magnetic and catalytic properties of cubic copper ferrite nanopowders synthesized from secondary resources. Adv. Powder Technol. 23, 315–323 (2012).

Article CAS Google Scholar

Goya, G. F., Rechenberg, H. R. & Jiang, J. Z. Structural and magnetic properties of ball milled copper ferrite. J. Appl. Phys. 84, 1101–1108 (1998).

Article ADS CAS Google Scholar

Marinca, T. F., Chicinaş, I. & Isnard, O. Structural and magnetic properties of the copper ferrite obtained by reactive milling and heat treatment. Ceram. Int. 39, 4179–4186 (2013).

Article CAS Google Scholar

Muhammad, A., Sattar, A. A., Elsayed, H. M. & Ghani, A. A. Microstructure, magnetic, optical and catalytic activity of Li–Co–Cd nanoferrites. J. Mater. Sci. Mater. Electron. 29, 3856–3866 (2018).

Article CAS Google Scholar

Mallesh, S. & Srinivas, V. A comprehensive study on thermal stability and magnetic properties of MnZn-ferrite nanoparticles. J. Magn. Magn. Mater. 475, 290–303 (2019).

Article ADS CAS Google Scholar

Gul, I. H., Maqsood, A., Naeem, M. & Ashiq, M. N. Optical, magnetic and electrical investigation of cobalt ferrite nanoparticles synthesized by co-precipitation route. J. Alloys Compd. 507, 201–206 (2010).

Article CAS Google Scholar

Faramawy, A., Elsayed, H., Scian, C. & Mattei, G. Structural, optical, magnetic and electrical properties of sputtered ZnO and ZnO: Fe thin films: the role of deposition power. Ceramics 5, 1128–1153 (2022).

Article CAS Google Scholar

Moumen, N. & Pileni, M. P. Control of the size of cobalt ferrite magnetic fluid. J. Phys. Chem. 100, 1867–1873 (1996).

Article CAS Google Scholar

Xu, Y. et al. Preparation and magnetic properties of ZnFe2O4 nanotubes. J. Nanomater. 2011, 1–6 (2011).

Google Scholar

Bohra, M. et al. Competing magnetic interactions in inverted Zn-ferrite thin films. Magnetism 2, 168–178 (2022).

Article Google Scholar

Iacovita, C. et al. Polyethylene glycol-mediated synthesis of cubic iron oxide nanoparticles with high heating power. Nanoscale Res. Lett. https://doi.org/10.1186/s11671-015-1091-0 (2015).

Article PubMed PubMed Central Google Scholar

Raghavender, A. T. et al. Synthesis and magnetic properties of NiFe2-xAlxO4 nanoparticles. J. Magn. Magn. Mater. 316, 1–7 (2007).

Article ADS CAS Google Scholar

Kahil, H. & El-Sayed, H. M. Assessment of AC losses in cobalt ferrite nanoparticles using a varying frequency induction heater. IOSR J. Appl. Phys. 7, 37–43 (2015).

Google Scholar

Sattar, A. A., Elsayed, H. M. & Faramawy, A. M. Comparative study of structure and magnetic properties of micro- and nano-sized GdxY3-xFe5O12 garnet. J. Magn. Magn. Mater. 412, 172–180 (2016).

Article ADS CAS Google Scholar

Vallejo-Fernandez, G. et al. Mechanisms of hyperthermia in magnetic nanoparticles. J. Phys. D. Appl. Phys. 46, 312001 (2013).

Article Google Scholar

Wildeboer, R. R., Southern, P. & Pankhurst, Q. A. On the reliable measurement of specific absorption rates and intrinsic loss parameters in magnetic hyperthermia materials. J. Phys. D. Appl. Phys. 47, 495003 (2014).

Article Google Scholar

Motoyama, J. et al. Hyperthermic treatment of DMBA-induced rat mammary cancer using magnetic nanoparticles. Biomagn. Res. Technol. 6, 1–6 (2008).

Article Google Scholar

Hergt, R., Dutz, S. & Zeisberger, M. Validity limits of the Néel relaxation model of magnetic nanoparticles for hyperthermia. Nanotechnology 21, 015706 (2010).

Article ADS PubMed Google Scholar

Kötitz, R., Weitschies, W., Trahms, L. & Semmler, W. Investigation of Brownian and Néel relaxation in magnetic fluids. J. Magn. Magn. Mater. 201, 102–104 (1999).

Article ADS Google Scholar

Lemine, O. M., Madkhali, N., Hjiri, M., All, N. A. & Aida, M. S. Comparative heating efficiency of hematite (α-Fe2O3) and nickel ferrite nanoparticles for magnetic hyperthermia application. Ceram. Int. 46, 28821–28827 (2020).

Article CAS Google Scholar

Download references

Open access funding provided by The Science, Technology & Innovation Funding Authority (STDF) in cooperation with The Egyptian Knowledge Bank (EKB).

Department of Physics, Faculty of Science, Ain Shams University, Abbassia, 11566, Cairo, Egypt

A. M. Faramawy & H. M. El-Sayed

You can also search for this author in PubMed Google Scholar

You can also search for this author in PubMed Google Scholar

A.M.F. and H.M.E.-S. handling the experimental work, analyzed the data, wrote and editing the manuscript.

Correspondence to A. M. Faramawy.

The authors declare no competing interests.

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/.

Reprints and permissions

Faramawy, A.M., El-Sayed, H.M. Enhancement of magnetization and optical properties of CuFe2O4/ZnFe2O4 core/shell nanostructure. Sci Rep 14, 6935 (2024). https://doi.org/10.1038/s41598-024-57134-7

Download citation

Received: 25 November 2023

Accepted: 14 March 2024

Published: 23 March 2024

DOI: https://doi.org/10.1038/s41598-024-57134-7

Anyone you share the following link with will be able to read this content:

Sorry, a shareable link is not currently available for this article.

Provided by the Springer Nature SharedIt content-sharing initiative